Concepts of High-Temperature Aquifer Thermal Energy Storage (HT-ATES) are investigated for system application in the German Molasse Basin. We quantify via physics-based numerical modelling the system performance with respect to HT-ATES concept development and provide a predictive analysis of HT-ATES application in the Upper Jurassic reservoir. Results demonstrate a non-uniform layer-specific distribution of the thermal front propagation, while promising heat recovery efficiencies are predicted.